“shim” for AngularJS (& jQuery ) when using Require.js

The rule is pretty simple: if a library/script/package/plugin is AMD-aware, then you don't need a shim. (Actually, you must not use a shim for it.) If it is not AMD-aware, then you need a shim.
A library/etc is AMD-aware if it detects that an AMD loader is present and calls define to make itself known to the loader.
jQuery from about 1.8 onwards has not needed a shim because it calls define. Angular, on the other hand, does not call define.
To know whether a specific piece of code needs a shim, you can read its documentation or if the documentation is not clear on this, then you can check the source code for a call to define. For instance jQuery 1.11.0 has this code:

// Register as a named AMD module, since jQuery can be concatenated with other
// files that may use define, but not via a proper concatenation script that
// understands anonymous AMD modules. A named AMD is safest and most robust
// way to register. Lowercase jquery is used because AMD module names are
// derived from file names, and jQuery is normally delivered in a lowercase
// file name. Do this after creating the global so that if an AMD module wants
// to call noConflict to hide this version of jQuery, it will work.
if ( typeof define === "function" && define.amd ) {
    define( "jquery", [], function() {
        return jQuery;
    });
}

How it looks like will vary from one case to the other but the basic think you want to look for is the check that define exists, is a function, has the amd property set and the call to define.
(Note that jQuery is a special case where they decided to hard code the name of the module in the define call (first parameter: jquery). Generally the name of the module won't be present in the define call but will be left for RequireJS to infer on the basis of the file name.)

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